UNITED STATES

SECURITIES AND EXCHANGE COMMISSION 
Washington, D.C. 20549 

FORM 6-K

REPORT OF FOREIGN PRIVATE ISSUER PURSUANT TO RULE 13a-16 OR 15d-16 UNDER THE SECURITIES EXCHANGE ACT OF 1934

For the month of May, 2025.

Commission File Number: 001-37723

Enel Chile S.A. 
(Translation of Registrant’s Name into English)

Santa Rosa 76
Santiago, Chile 
(Address of principal executive office)

Indicate by check mark whether the registrant files or will file annual reports under cover of Form 20-F or Form 40-F.

Form 20-F  [X]   Form 40-F  [   ]

MATERIAL FACT

Enel Chile S.A.

Santiago, May 28, 2025

Gen. Mgmt. No.10/2025

Mrs.

Solange Bernstein Jáuregui

Chair

Financial Market Commission

1449 Libertador Bernardo O’Higgins Ave.

Santiago, Chile

Ref.:       Communicates Material Fact

Dear Madam:

In compliance with the provisions of Articles 9 and 10, second paragraph, of Law No. 18,045 and the provisions of General Rule No. 30 of the Financial Market Commission (“CMF” in its Spanish acronym), duly empowered and on behalf of Enel Chile S.A., I hereby inform you, as a material fact, that today, at an ordinary meeting of the Board of Directors, the Chief Executive Officer of the Company, Mr. Giuseppe Turchiarelli, tendered his resignation. This resignation is effective as of July 1, 2025.

Likewise, it is informed that in this meeting of the Board of Directors of Enel Chile S.A., Mr. Gianluca Palumbo was appointed as the new Chief Executive Officer of Enel Chile S.A., who will assume his duties as of July 1, 2025.

Sincerely yours,

Josefa Rodríguez Benavente

Secretary of the Board of Directors

Enel Chile S.A.

SIGNATURES

Pursuant to the requirements of the Securities Exchange Act of 1934, the registrant has duly caused this report to be signed on its behalf by the undersigned, thereunto duly authorized.

Date: May 28, 2025